Sulfur-assisted domino access to bicyclic dihydrofurans: case study and early synthetic applications.
نویسندگان
چکیده
A DDQ-mediated domino reaction (up to six steps in a single process) has been developed to selectively provide substituted dihydrofurans from a common starting material containing a cyclic bis-thioenol ether. Study of the reaction mechanism highlighted a role played by the sulfur-containing moiety in influencing reaction rate and stereoselectivity.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 11 45 شماره
صفحات -
تاریخ انتشار 2013